Integrated luminometer for the determination of trace metals in seawater using fluorescence, phosphorescence and chemiluminescence detection

一体化光度计,采用荧光、磷光和化学发光检测法测定海水中的痕量金属

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作者:P J Worsfold, E P Achterberg, A R Bowie, V Cannizzaro, S Charles, J M Costa, F Dubois, R Pereiro, B San Vicente, A Sanz-Medel, R Vandeloise, E Vander Donckt, P Wollast, S Yunus

Abstract

The paper describes an integrated luminometer able to perform fluorescence (FL), room temperature phosphorescence (RTP) and chemiluminescence (CL) measurements on seawater samples. The technical details of the instrumentation are presented together with flow injection (FI) manifolds for the determination of cadmium and zinc (by FL), lead (RTP) and cobalt (CL). The analytical figures of merit are given for each manifold and results are presented for the determination of the four trace metals in seawater reference materials (NASS-5, SLEW-2) and Scheldt estuarine water samples.

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