Textile Waste-Derived Cobalt Nanoparticles Embedded in Active Carbon Fiber for Efficient Activation of Peroxymonosulfate to Remove Organic Pollutants

纺织废料衍生的钴纳米颗粒嵌入活性碳纤维中,高效活化过氧单硫酸盐去除有机污染物

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作者:Peiyuan Xiao, Ying Wang, Huanzheng Du, Zhiyong Yan, Bincheng Xu, Guangming Li

Abstract

Burning and dumping textile wastes have caused serious damage to the environment and are a huge waste of resources. In this work, cobalt nanoparticles embedded in active carbon fiber (Co/ACF) were prepared from bio-based fabric wastes, including cotton, flax and viscose. The obtained Co/ACF was applied as a catalyst for the heterogeneous activation of peroxymonosulfate (PMS) to remove bisphenol A (BPA) from an aqueous solution. The results showed that cotton-, flax- and viscose-derived Co/ACF all exhibited excellent performance for BPA degradation; over ~97.0% of BPA was removed within 8 min. The Co/ACF/PMS system exhibited a wide operating pH range, with a low consumption of the catalyst (0.1 g L-1) and PMS (0.14 g L-1). The high specific surface area (342 m2/g) and mesoporous structure of Co/ACF allowed the efficient adsorption of pollutants as well as provided more accessible active sites for PMS activation. This study provided an example of using textile wastes to produce a valuable and recyclable catalyst for environmental remediation.

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