Abstract
Four novel choline carboxylate aqueous solution systems were developed by mixing H&sub2;O with choline nicotinate [Ch][Na], choline ferulate [Ch][Fa], choline vanillate [Ch][Va] and choline syringate [Ch][Sa]. The solubility of lignin in the four solvents was determined at 25 °C. The influence of the molar ratio of H&sub2;O to [Ch][Na] ([Ch][Fa], [Ch][Va] and [Ch][Sa]) and the anionic structure on lignin solubility were systematically investigated. It was found that, the anionic structure and H&sub2;O content significantly affected lignin dissolution. Interestingly, H&sub2;O/[Ch][Na] and H&sub2;O/[Ch][Fa] solvents show efficient capacity for lignin dissolution even at room temperatures. The dissolution of lignin in H&sub2;O/[Ch][Na] and H&sub2;O/[Ch][Fa] solvents is mainly ascribed to the interaction of lignin with the alkyl chain in the anion and cation dissociated from [Ch][Na]([Ch][Fa]) by H&sub2;O. In addition, the recycling of the lignin solvent was examined, and the structure and thermostability of the lignin regenerated from the solvent were also estimated.