Ag Functionalized In2O3 Derived From MIL-68(In) as an Efficient Electrochemical Glucose Sensor

源自 MIL-68(In) 的 Ag 功能化 In2O3 作为高效电化学葡萄糖传感器

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作者:Dooa Arif, Zakir Hussain, Amna Didar Abbasi, Manzar Sohail

Abstract

In this study, Ag@In2O3 modified nickel foam (NF) was reported for its role as a non-enzymatic glucose sensor. Ag@In2O3 was prepared by a simple two-step method; preparation of a metal-organic framework (MOF) MIL-68(In) by solvothermal method, entrapment of Ag + by adding AgNO3 then drying it for 2 h to complete the entrapment process and subsequent calcination at 650°C for 3 h. The Ag@In2O3 modified NF was employed as a non-enzymatic glucose sensor to determine glucose concentrations in an alkaline medium. Two linear ranges were obtained from Ag@In2O3 modified electrode, i.e., 10 μM to 0.8 mM and 0.8-2.16 mM with a sensitivity of 3.31 mA mM-1 cm-2 and 1.51 mA mM-1 cm-2 respectively, with a detection limit of 0.49 µM. Ag@In2O3 modified NF exhibited high selectivity for glucose, among other interfering agents.

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