Molecular Encapsulation from the Liquid Phase and Graphene Nanoribbon Growth in Carbon Nanotubes

液相分子封装及碳纳米管中石墨烯纳米带的生长

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作者:Ana Cadena, Bea Botka, Áron Pekker, Cla Duri Tschannen, Chiara Lombardo, Lukas Novotny, Andrei N Khlobystov, Katalin Kamarás

Abstract

Growing graphene nanoribbons from small organic molecules encapsulated in carbon nanotubes can result in products with uniform width and chirality. We propose a method based on encapsulation of 1,2,4-trichlorobenzene from the liquid phase and subsequent annealing. This procedure results in graphene nanoribbons several tens of nanometers long. The presence of nanoribbons was proven by Raman spectra both on macroscopic samples and on the nanoscale by tip-enhanced Raman scattering and high-resolution transmission electron microscopic images.

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