Background
The development of green chemistry
Conclusions
In conclusion, the best MB dye degradation capacity belonged to co-precipitation ZnO nanoparticles followed by S. officinalis and A. esculentus nanoparticles.
Methods
To compare the properties of ZnO nanoparticles, another type of ZnO-NPs was synthesized using the co-precipitation method. The characterization of synthesized nanoparticles was performed using thermogravimetric analysis (TGA-DTG), X-ray diffraction (XRD), Dynamic Light Scattering (DLS), Zeta potential (ZP), field emission scanning electron microscopy (FE-SEM), Energy Dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), and UV-Vis spectrophotometry.
Results
Based on XRD results, the average crystalline size of nanoparticles was calculated using the Debye-Scherer equation for synthesized nanoparticles using the S. officinalis at 22.99 nm and for the A. esculentus at 29.79 nm, and for the co-precipitation method at 18.83 nm. The FE-SEM images showed spherical ZnO nanoparticles. Photocatalytic properties of ZnO-NPs were investigated for remove of methylene blue organic dye in the presence of UV light. The pH 10 was identified as the best pH, which had the highest percentage of color degradation. All three types of nanoparticles were tested by up to 360 min to optimize the dyeing time. For A. esculentus, the highest percentage of color removal occurred in the first 90 min (41.0 %), for S. officinalis nanoparticles between 75 and 90 min (86.9 %), and for chemically synthesized nanoparticles between 30 and 45 min (100 %). Conclusions: In