Synthesis and application of gas diffusion cathodes in an advanced type of undivided electrochemical cell

气体扩散阴极的合成及其在先进无隔膜电化学电池中的应用

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作者:S Z J Zaidi, Y Luan, C Harito, L Utari, B Yuliarto, F C Walsh

Abstract

This paper reports the oxidation of Remazol black B dye by employing iron ions catalyst based gas diffusion cathodes, (GDCs). A GDC was synthesized by using a layer of carbon black and iron ions catalyst for oxygen reduction to hydrogen peroxide. The results demonstrated around 97% decolorization of Remazol black-B dye for 50 min by iron ions catalyst based GDC. The degradation study was performed under electrogenerated hydrogen peroxide at a constant voltage of - 0.6 V vs Hg/HgSO4 in which the rate of degradation was correlated with hydrogen peroxide production. Overall, the GDC's found to be effective method to degrade the dyes via electro-Fenton.

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