Efficient electrochemical remediation of microcystin-LR in tap water using designer TiO2@carbon electrodes

使用设计 TiO2@碳电极对自来水中的微囊藻毒素-LR 进行高效电化学修复

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作者:Germán Sanz Lobón, Alfonso Yepez, Luane Ferreira Garcia, Ruiter Lima Morais, Boniek Gontijo Vaz, Veronica Vale Carvalho, Gisele Augusto Rodrigues de Oliveira, Rafael Luque, Eric de Souza Gil

Abstract

Microcystin-leucine arginine (MC-LR) is the most abundant and toxic secondary metabolite produced by freshwater cyanobacteria. This toxin has a high potential hazard health due to potential interactions with liver, kidney and the nervous system. The aim of this work was the design of a simple and environmentally friendly electrochemical system based on highly efficient nanostructured electrodes for the removal of MC-LR in tap water. Titania nanoparticles were deposited on carbon (graphite) under a simple and efficient microwave assisted approach for the design of the electrode, further utilized in the electrochemical remediation assays. Parameters including the applied voltage, time of removal and pH (natural tap water or alkaline condition) were investigated in the process, with results pointing to a high removal efficiency for MC-LR (60% in tap water and 90% in alkaline media experiments, under optimized conditions).

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