Ag nanoparticles immobilized on new magnetic alginate halloysite as a recoverable catalyst for reduction of nitroaromatics in aqueous media

固定在新型磁性海藻酸盐埃洛石上的银纳米粒子作为可回收催化剂用于还原水性介质中的硝基芳族化合物

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作者:Pourya Mohammadi, Majid Heravi, Mansoureh Daraie

Abstract

Amines can be applied in the synthesis of various important compounds such as dyes, drugs, polymers, pharmaceutical products, and biologically active materials. The significant subject in the preparation of amines is the selection of the most effective heterogeneous catalyst to get the best catalytic efficiency, stability, recoverability, and reusability. For this target, we prepared new alginate magnetically recoverable nanocatalyst by stabilization of Ag nanoparticles on the surface of the halloysite (HS) [HS-Alginate-Ag/Fe3O4]. Several detection methods confirmed the production of HS-Alginate-Ag/Fe3O4 nanocatalyst and the results obtained were well explained in the context. HS-Alginate-Ag/Fe3O4 presented good catalytic performance for the hydrogenation of nitro compounds using NaBH4 as the reducing agent and hydrogen donor. The good activity and durability of this catalyst can be attributed to the good dispersion and nano-sized particle of silver nanoparticles.

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