Lithium Titanate/Carbon Nanotubes Composites Processed by Ultrasound Irradiation as Anodes for Lithium Ion Batteries

超声辐照制备钛酸锂/碳纳米管复合材料作为锂离子电池负极

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作者:João Coelho, Anuj Pokle, Sang-Hoon Park, Niall McEvoy, Nina C Berner, Georg S Duesberg, Valeria Nicolosi

Abstract

In this work, lithium titanate nanoparticles (nLTO)/single wall carbon nanotubes (SWCNT) composite electrodes are prepared by the combination of an ultrasound irradiation and ultrasonic spray deposition methods. It was found that a mass fraction of 15% carbon nanotubes optimizes the electrochemical performance of nLTO electrodes. These present capacities as high as 173, 130, 110 and 70 mAh.g-1 at 0.1C, 1C, 10C and 100C, respectively. Moreover, after 1000 cycles at 1C, the nLTO/SWCNT composites present a capacity loss of just 9% and a Coulombic efficiency of 99.8%. Therefore, the presented methodology might be extended to other suitable active materials in order to manufacture binder free electrodes with optimal energy storage capabilities.

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