Impact of the Chemical Structure of Photoreactive Urethane (Meth)Acrylates with Various (Meth)Acrylate Groups and Built-In Diels-Alder Reaction Adducts on the UV-Curing Process and Self-Healing Properties

具有各种(甲基)丙烯酸酯基团和内置狄尔斯-阿尔德反应加合物的光反应性聚氨酯(甲基)丙烯酸酯的化学结构对紫外固化过程和自修复性能的影响

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作者:Paulina Bednarczyk, Karolina Mozelewska, Joanna Klebeko, Joanna Rokicka, Paula Ossowicz-Rupniewska

Methods

an FTIR spectroscope equipped with a heating attachment; DSC and TG apparatus; and an optical microscope equipped with a stage with programmable heating. The result of comprehensive research on the self-healing of photocurable coatings in the context of the presence of various photoreactive groups and the course of the curing process allows one to control the self-healing process by reducing the effective healing temperature. The self-healing properties, taken together with the fast UV curing of the coatings and excellent properties of cured coatings, make the material attractive for a variety of applications, in particular in cases where coatings are not repaired, e.g., for economic reasons or when it is not possible, such as in flexible electronic screens, car paint film, and aircraft interior finishes.

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