An unprecedented spin cluster-based network architecture {[Ni(II) (2) (pdaa)(OH)(2) (H(2) O)](n) (H(2) pdaa=1,4-phenylene diacetic acid)}, comprising 1D linear chains of Ni(II) ions crosslinked via Ni(4) O(4) cubanes, forms under hydrothermal conditions; this 3D coordination network exhibits magnetic ordering at 23.9â K as well as a second magnetic ordering process at 2.8â K likely associated with a structural phase transition.
Magnetic Phase Transitions in a Ni(4) O(4) -Cubane-Based Metal-Organic Framework.
Ni(4)O(4)-立方烷基金属有机框架中的磁相变
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作者:Nadeem Muhammad Arif, Ng Maggie Chai Cin, van Leusen Jan, Kögerler Paul, Stride John Arron
| 期刊: | Chemistry | 影响因子: | 2.400 |
| 时间: | 2020 | 起止号: | 2020 Jun 18; 26(34):7589-7594 |
| doi: | 10.1002/chem.202000867 | 研究方向: | 其它 |
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