Calcined Bean Dregs-Hydrocalumite Composites as Efficient Adsorbents for the Removal of Ofloxacin.

Calcined bean dregs-hydrocalumite composites were prepared through in situ self-assembly of hydrocalumite on the surface of bean dregs and used for the adsorption of ofloxacin from water. The adsorbents were characterized by scanning electron microscopy, X-ray powder diffraction, and N(2) physical adsorption. The results showed that the adsorption performance of calcined bean dregs-hydrocalumite composites for ofloxacin was much better than that of a single bean dreg carbon or calcined hydrocalumite. The effects of preparation and adsorption conditions on the adsorption property of calcined bean dregs-hydrocalumite for ofloxacin were also investigated. The adsorption ratio of ofloxacin reached up to 99.93% using 4 g·L(-1) adsorbent dosage with 20 mg·L(-1) initial concentration of ofloxacin at 30 °C in 2 h. The adsorption process mainly occurred in the first 5 min. In addition, the adsorption of ofloxacin by calcined bean dregs-hydrocalumite was more in line with pseudo-second-order dynamics and the Langmuir isotherm model.