Bis[3,5-di-fluoro-2-(pyridin-2-yl)phen-yl](4,4'-di-meth-oxy-2,2'-bi-pyridine)-iridium(III) hexa-fluorido-phosphate.

The title cyclo-metalated distorted octa-hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir-N bonds to the dimeth-oxy bi-pyridine ligand [2.128†(3) and 2.136†(3)†à ] where these nitro-gen atoms are trans to the Ir-C bonds of the two cyclo-metalating di-fluoro-phenyl-pyridine ligands. The angles between the mean planes of the phenyl and pyridyl fragments within the individual ligands range from 3.5†(2) to 11.4†(2)° to deviate slightly from coplanarity.