In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}(n), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N-Hâ¯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butyl-isophthalate ligands. One of the Zn atoms displays a tetra-hedral coordination environment, while the other Zn atom adopts a five-coordinate geometry inter-mediate between square pyramidal and trigonal bipyramidal. Additionally, O-Hâ¯O hydrogen-bonding patterns involving the water mol-ecules of crystallization serve as a structure-stabilizing element by aggregating the double-strand motifs.
Poly[[aqua-[μ(2)-1,3-bis-(pyridin-4-yl)urea-κ(2)N(4):N(4')]bis-(μ(3)-5-tert-butyl-isophthalato-κ(3)O(1):O(1'):O(3))dizinc(II)] trihydrate], a double-strand coordination polymer.
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作者:Jia Jason, LaDuca Robert L
| 期刊: | IUCrdata | 影响因子: | 0.000 |
| 时间: | 2023 | 起止号: | 2023 Aug 4; 8(Pt 8):x230659 |
| doi: | 10.1107/S2414314623006594 | ||
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