In the title compound, C(17)H(10)F(6)N(4)O(2)S, an intra-molecular N-Hâ¯N hydrogen bonds forms an S(5) ring whereas N-Hâ¯O and C-Hâ¯S inter-actions complete S(6) ring motifs. The dihedral angle between the fused ring system and the phenyl ring is 6.68â (8)°. In the crystal, the mol-ecules are dimerized due to N-Hâ¯O inter-actions. Ï-Ï inter-actions are present between the benzene rings [centroid-centroid distance = 3.6913â (15)â à ] and between the five membered ring and the trifluoro-meth-yl)phenyl ring [centroids-centroid distance = 3.7827â (16)â à ]. One of the trifluoro-meth-oxy F atoms is disordered over two sites with occupancy ratio of 0.76â (3):0.24â (3). The F atoms of the p-trifluoro-methyl substituent are disordered over three sets of sites with an occupancy ratio of 0.70â (2):0.152â (11):0.147â (13).
1-[2-Oxo-5-(trifluoro-meth-oxy)indolin-3-yl-idene]-4-[4-(trifluoro-methyl)-phen-yl]thio-semicarbazide.
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作者:Pervez Humayun, Iqbal Mohammad S, Saira Naveeda, Yaqub Muhammad, Tahir M Nawaz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jun 23; 66(Pt 7):o1749 |
| doi: | 10.1107/S1600536810023494 | ||
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