The asymmetric unit of the title compound, C(17)H(12)ClF(3)N(4)O(2)S, contains two mol-ecules, which differ in their planarity and hydrogen bonding. In one mol-ecule, the 2-oxoindolin (C(8)/N/O A), thio-semicarbazide (N(3)/C/S B) and 5-chloro-2-methyl-phenyl (C(7)/Cl C) units are planar with r.m.s. deviations of 0.0110, 0.0173 and 0.0259â à , respectively. The dihedral angles A/B, B/C and A/C are 1.74â (15), 40.70â (13) and 41.00â (11)°, respectively. In the other mol-ecule the deviations are 0.0455, 0.0007 and 0.0143â à , respectively, and the dihedral angles are 5.01â (14), 4.53â (16) and 3.38â (13)°, respectively. In both mol-ecules, intra-molecular N-Hâ¯N and N-Hâ¯O hydrogen bonds form S(5) and S(6) ring motifs, respectively and C-Hâ¯S interactions occur. In one of the molecules, an intramolecular C-Hâ¯F interaction is also present. In the crystal, the mol-ecules are linked by N-Hâ¯O, C-Hâ¯F, C-Hâ¯O and N-Hâ¯S hydrogen bonding, forming a polymeric network.
4-(5-Chloro-2-methyl-phen-yl)-1-[2-oxo-5-(trifluoro-meth-oxy)indolin-3-yl-idene]thio-semicarbazide.
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作者:Pervez Humayun, Iqbal Mohammad S, Saira Naveeda, Yaqub Muhammad, Tahir M Nawaz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Apr 24; 66(Pt 5):o1169-70 |
| doi: | 10.1107/S1600536810014650 | ||
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