In the title compound, [Zn(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)](n), the Zn(II) ion is tetrahedrally coordinated by two formyl-benzoate (FB) and one isonicotinamide (INA) ligands while symmetry-related FB ligands bridge adjacent Zn(II) ions, forming polymeric chains along the b axis. The carboxyl-ate groups in the two FB ions are twisted away from the attached benzene ring by 9.07â (2) and 26.2â (2)°. The two benzene rings of the FB ions are oriented at a dihedral angle of 81.30â (5)°. In the crystal, adjacent polymeric chains inter-act via N-Hâ¯O and C-Hâ¯O hydrogen bonds, Ï-Ï contacts between the formyl-benzoate rings [centroid-centroid distance = 3.7736â (8)â à ] and weak C-Hâ¯Ï inter-actions, forming a three-dimensional network.
catena-Poly[[(4-formyl-benzoato-κO)(isonicotinamide-κN)zinc(II)]-μ-4-formyl-benzoato-κO:O].
阅读:10
作者:Hökelek Tuncer, Yılmaz Filiz, Tercan BarıÅ, Sertçelik Mustafa, NecefoÄlu Hacali
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Oct 23; 65(Pt 11):m1399-400 |
| doi: | 10.1107/S160053680904241X | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
