In the title compound, C(32)H(26)BN(5) or [(C(14)H(11)N(5))B(C(6)H(5))(3)], the B atom is approximately tetra-hedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C-Hâ¯Ï inter-actions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°.
Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron.
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作者:Urakami Daisuke, Inoue Katsuya, Hayami Shinya
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Sep 9; 65(Pt 10):o2425 |
| doi: | 10.1107/S1600536809036071 | ||
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