In the title di-hydro-dioxin, C31H28O5, the dioxane ring has a chair conformation, whereas each of the pyran and dioxine rings has an envelope conformation with methyl-ene and quaternary C atoms, respectively, being the flap atoms. The phenyl rings are cis and form a dihedral angle of 82.11â (10)°. The molecular structure is stabilized by C-Hâ¯O contacts. In the crystal packing, supra-molecular layers parallel to (101) are sustained by C-Hâ¯Ï inter-actions.
3,3-Dimethyl-cis-9a,13a-diphenyl-2,3,9a,11,12,13a-hexa-hydro-1H-benzo[h][1,4]dioxino[2',3':5,6][1,4]dioxino[2,3-f]chromene.
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作者:Bernardes Bauer O, Ferreira Aurelio B Buarque, Wardell James L, Wardell Solange M S V, Netto-Ferreira José C, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Aug 31; 69(Pt 9):o1487-8 |
| doi: | 10.1107/S1600536813023660 | ||
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