The title compound, C(17)H(17)NO(3), crystallizes in a zwitterionic form with cationic iminium and anionic enolate groups. The zwitterion exists in a trans configuration about the C=N bond. The dihedral angle between the two benzene rings is 13.42â (7)°. The meth-oxy group is almost coplanar [C-O-C-C = 2.1â (2)°] with the attached ring whereas the allyl unit is oriented at a dihedral angle of 67.9â (1)°. An intra-molecular N-Hâ¯O hydrogen bond generates an S(6) ring motif. In the crystal, the mol-ecules are linked into zigzag chains along [010] by O-Hâ¯O hydrogen bonds. In addition, weak C-Hâ¯Ï inter-actions are observed.
(E)-4-Allyl-2-[(2-hydroxy-phen-yl)iminiometh-yl]-6-methoxy-phenolate.
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作者:Eltayeb Naser Eltaher, Teoh Siang Guan, Chantrapromma Suchada, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Mar 27; 66(Pt 4):o934-5 |
| doi: | 10.1107/S160053681000838X | ||
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