Combining Source Rock Kinetics and Vitrinite Reflectance in Source Rock Evaluation of the Bakken Formation, Williston Basin, USA.

The elements of Bakken Petroleum System consist of two source rocks with high underlying burial depths for significant hydrocarbon generation. However, this deep hydrocarbon generation process is dependent on its kinetic properties, thermal maturity, and geochemical properties. The statistical compensation effect is a complicating factor in the kinetic analyses of the Bakken Formation. In this study, we experimentally determined the kinetics of the Bakken formation source beds, observed the presence of the residual compensation effect, and numerically established a correlation between the kinetic parameters, thermal maturity indices (T (max)), and the vitrinite reflectance (VR(o)) and bitumen reflectance (BR(o)). First, we conducted source rock analysis to determine kinetic properties and the organic geochemical assays of reactive kerogen in the Bakken source beds. Finally, we incorporated previous established studies to generate numerical correlation for T (max) in terms of VR(o) and BR(o) reflectance. Our kinetic results show evidence of the residual compensation effect in the Bakken Formation when samples are repeatedly analyzed. The simultaneous linear expression of the residual compensation effect and the regression analysis of the solutions to the Kissinger equation for heating rate, yielded a kinetic parameter solution that correlates with T (max). Furthermore, recalculated T (max) values established a correlation between the kinetic parameters, T (max), VR(o), and BR(o). The application of state-of-the-art numerical correlations to measure subsurface kinetics, source rock richness, and burial-depth temperatures will enhance the accuracy of reservoir exploration and hydrocarbon production within the Bakken Formation.