In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(-), there are two crystallographically independent mol-ecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene rings is 6.53â (7)° for one mol-ecule and 5.30â (7)° for the other. The meth-oxy groups in the anion mol-ecules are each twisted from the mean plane of benzene ring with torsion angles of 16.38â (19) and 4.32â (19)°. In the crystal structure, the cations are stacked in an anti-parallel manner along the a axis and the anions are linked together by C-Hâ¯O inter-actions into a layer parallel to (001). The anion layers are further linked to adjacent cations by C-Hâ¯O inter-actions. C-Hâ¯Ï inter-actions involving the benzene rings of both ions are also observed.
2-[(E)-2-(4-Chloro-phen-yl)ethen-yl]-1-methyl-pyridinium 4-methoxy-benzene-sulfonate.
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作者:Chanawanno Kullapa, Chantrapromma Suchada, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Jun 10; 65(Pt 7):o1549-50 |
| doi: | 10.1107/S1600536809021679 | ||
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