In the title compound, C10H6F2N4, the Car-N bonds are slightly shortened with respect to a standard aniline C-N bond [1.3580â (16) and 1.3618â (16) versus 1.39â à ], thus indicating some Ï-Ï conjgation with the electron-acceptor CN groups. The mol-ecule, except for two C atom of the ethyl-ene bridge, is nearly planar, the largest deviation of the other non-H atoms from the mean plane being 0.309â (2)â à . The N-C-C-N torsion angle involving the ethyl-ene bridge is 50.23â (18)°. In the crystal, mol-ecules are connected by pairs of N-Hâ¯N hydrogen bonds into chains along [21-1].
6,7-Difluoro-1,2,3,4-tetra-hydro-quin-oxa-line-5,8-dicarbonitrile.
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作者:Qu Bao-Hua, Jia Xiao-Chuan, Li Jing, He Ming-Yang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Mar 1; 69(Pt 3):o376 |
| doi: | 10.1107/S1600536813003206 | ||
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