The title compound crystallizes as a hemihydrate, C18H20N2O5·0.5H2O. The mol-ecule exists in an E conformation with respect to the C=N imine bond. The 4-meth-oxy-phenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54â (2):0.46â (2). The dihedral angles between the benzene rings are 29.20â (9) and 26.59â (9)°, respectively, for the major and minor components of the 4-meth-oxy-substituted ring. All meth-oxy substituents lie close to the plane of the attached benzene rings [the Cmeth-yl-O-C-C torsion angles range from -4.0â (12) to 3.9â (2)°]. In the crystal, the components are linked into chains propagating along [001] via N-Hâ¯O and O-Hâ¯O hydrogen bonds and weak C-Hâ¯O inter-actions.
(E)-4-Meth-oxy-N'-(2,4,5-tri-meth-oxy-benzyl-idene)benzohydrazide hemihydrate.
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作者:Chantrapromma Suchada, Boonnak Nawong, Horkaew Jirapa, Quah Ching Kheng, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Jan 15; 70(Pt 2):o150-1 |
| doi: | 10.1107/S1600536814000531 | ||
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