In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetra-dentate Schiff base ligand. The asymmetric unit comprises one complex mol-ecule and a water mol-ecule of crystallization. The water H atoms form bifurcated O-Hâ¯(O,O) inter-molecular hydrogen bonds with the O atoms of the phenolate and eth-oxy groups with R(1) (2)(5) and R(1) (2)(6) ring motifs, which may, in part, influence the mol-ecular configuration. The dihedral angle between the two O-Cu-N coordination planes is 31.02â (6)° and the dihedral angle between the two benzene rings is 34.98â (7)°. In the crystal structure, mol-ecules are linked together by inter-molecular C-Hâ¯O inter-actions, forming extended chains along the a axis. The crystal structure is further stabilized by inter-molecular C-Hâ¯Ï and Ï-Ï [centroid-centroid = 3.5068â (13)â à ] inter-actions.
{6,6'-Dieth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}copper(II) monohydrate.
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作者:Kargar Hadi, Kia Reza, Fun Hoong-Kun, Jamshidvand Arezoo
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Apr 10; 65(Pt 5):m515-6 |
| doi: | 10.1107/S1600536809012859 | ||
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