Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter-actions.

Bis[triamminesilver(I)] bis-[diamminesilver(I)] hexa-fluorido-stannate(IV) difluoride, [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), was obtained in the form of colourless crystals from the reaction of CsAgSnF(7) in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag⋯Ag distances in the range of argentophilic inter-actions. In the crystal, several N-H⋯F hydrogen bonds are present between the complex cations and the SbF(6)(-) and F(-) anions, leading to the formation of a three-dimensional network.