In the title mol-ecule, C(22)H(23)O(4)PSe, the P atom has a distorted tetra-hedral environment formed by the selenide atom [P=Se = 2.1219â (5)â à ] and three aryl rings. The orientations of the meth-oxy groups in the two 2,4-dimeth-oxy-phenyl ligands are distinct, as seen from the torsion angles: C-C-O-C = 14.7â (3) and 175.97â (17)° in one ligand, and -9.1â (2) and 5.1â (3)° in the other. In the crystal, weak inter-molecular C-Hâ¯Se inter-actions link the mol-ecules into zigzag chains propagated in [010].
Bis(2,4-dimeth-oxy-phen-yl)(phen-yl)phosphine selenide.
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作者:Muller, Alfred
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Dec 11; 67(Pt 1):o97 |
| doi: | 10.1107/S1600536810049366 | ||
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