In the title copper(II) salt, [Cu(C(6)H(6)N(4))(2)(C(2)H(6)OS)(2)](BF(4))(2), the Jahn-Teller distorted octa-hedral coordination sphere of copper is formed from four 2,2'-bi-1H-imidazole N atoms and two dimethyl sulfoxide O atoms. The Cu atom lies on a center of inversion. N-Hâ¯O and N-Hâ¯F hydrogen bonds give rise to a one-dimensional structure. The BF(4) (-) anion is disordered over two sites in a 0.671â (10):0.329â (10) ratio.
Bis(2,2'-bi-1H-imidazole-κN,N)bis-(dimethyl sulfoxide-κO)copper(II) bis-(tetra-fluoridoborate).
双(2,2'-联-1H-咪唑-κN,N)双-(二甲基亚砜-κO)铜(II)双-(四氟硼酸盐)
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作者:Dai Yong-Cheng, Jin Qiong-Hua, Cui Li-Na, Xu Li-Jun, Zhang Cun-Lin
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Aug 18; 66(Pt 9):m1124-5 |
| doi: | 10.1107/S1600536810031922 | ||
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