In the title mol-ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra-chloridocobaltate(II) anion is significantly distorted from regular tetra-hedral geometry [Cl-Co-Cl = 102.183â (19)-117.59â (2)°]. The Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-Hâ¯O and N-Hâ¯Cl and bifurcated N-Hâ¯(O,Cl) hydrogen bonds to generate (100) sheets.
Dimorpholinium tetra-chlorido-cobaltate(II).
二吗啉四氯化钴(II)
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作者:Cao Xing-Xing, Cheng He-Long, Feng Qing-Liu, Chen Li-Zhuang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Sep 1; 68(Pt 9):m1198 |
| doi: | 10.1107/S1600536812035830 | ||
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