Dimorpholinium tetra-chlorido-cobaltate(II).

二吗啉四氯化钴(II)

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作者:Cao Xing-Xing, Cheng He-Long, Feng Qing-Liu, Chen Li-Zhuang
In the title mol-ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra-chloridocobaltate(II) anion is significantly distorted from regular tetra-hedral geometry [Cl-Co-Cl = 102.183†(19)-117.59†(2)°]. The Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-H⋯O and N-H⋯Cl and bifurcated N-H⋯(O,Cl) hydrogen bonds to generate (100) sheets.

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