The title dinuclear copper complex, [Cu(2)Br(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cu(II) ion is in a slightly distorted square-pyramidal environment in which the N atoms of a dipicolyl-amine group and a bromide ligand form the basal plane. The apical site is occupied by a second Br atom. While the Cu-N distances involving the pyridine N atoms are the same within experimental error, the Cu-N distance involving the tertiary N atom is slightly elongated. Due to the typical Jahn-Teller distortion of copper(II) complexes, the apical Cu-Br distance is elongated.
μ-N,N,N',N'-Tetra-kis(2-pyridyl-meth-yl)butane-1,4-diamine]-bis-[dibromidocopper(II).
μ-N,N,N',N'-四-(2-吡啶基甲基)丁烷-1,4-二胺]-双-[二溴铜(II).
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作者:Bartholomä Mark, Cheung Hoi, Zubieta Jon
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Sep 4; 66(Pt 10):m1198 |
| doi: | 10.1107/S1600536810034537 | ||
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