The title Cu(II) coordination polymer, {[Cu(C(7)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2)·H(2)O}(n), was obtained by the reaction of equimolar Cu(NO(3))(2)·4H(2)O and 1,3-bis-(1,2,4-triazol-1-yl)propane (btp) in a water-methanol solvent. The Cu(II) atom is located on a centre of inversion and has an elongated octa-hedral coordination geometry formed by four N atoms from four symmetry-related btp ligands and two coordinated water mol-ecules. Adjacent Cu(II) atoms are connected by btp ligands, generating a double-stranded chain. The nitrate anion is disordered over two positions in a 0.828â (7):0.172â (2) ratio.
catena-Poly[[[diaqua-copper(II)]-bis-[μ(2)-1,3-bis-(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate].
catena-聚[[[二水合铜(II)]-双-[α(2)-1,3-双-(1,2,4-三唑-1-基)丙烷]]二硝酸盐一水合物]
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作者:Feng Wen, Zhao Xiao-Jun, Yang En-Cui
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Sep 12; 65(Pt 10):m1198-9 |
| doi: | 10.1107/S1600536809035958 | ||
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