The Pb(II) atom in the polymeric title compound, [Pb(C(8)H(4)O(4))(C(12)H(6)N(2)O(2))](n), is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The Pb(II) atom is stereochemically active in a Ï-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pbâ¯O inter-actions are considered, the geometry is a Ï-dodeca-hedron.
catena-Poly[[(1,10-phenanthroline-5,6-dione-κN,N')lead(II)]-μ-terephthalato-κO:O].
链状聚[[(1,10-菲咯啉-5,6-二酮-γN,N')铅(II)]-γ-对苯二甲酸-γO:O]
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作者:Cong Fang-Di, Yu Feng-Yang, Wei Zhen, Ng Seik Weng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Nov 7; 65(Pt 12):m1544 |
| doi: | 10.1107/S1600536809046455 | ||
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