In the title compound, [Fe(2)(C(7)H(4)IN)(C(3)H(6)S(2))(CO)(5)], the Fe-Fe distance of 2.5156â (11)â à compares well with that in related model structures. The phenyl isocyanide ligand is in the basal position and trans to the S atoms of the propane-dithiol-ate ligand due to steric hindrance. The crystal structure features C-Hâ¯O inter-actions.
Penta-carbonyl-1κC,2κC-(4-iodo-phenyl isocyanide-1κC)(μ-propane-1,3-dithiol-ato-1:2κS,S':S,S')iron(I)(Fe-Fe).
五羰基-1℃,2℃-(4-碘苯基异氰化物-1℃)(μ-丙烷-1,3-二硫醇-ato-1:2℃S,S':S,S')铁(I)(Fe-Fe)
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作者:Zhu Jinli, Tang Yanfeng, Jiang Guo-Min, Wang Miao, Hua Ping
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):m1753-4 |
| doi: | 10.1107/S1600536811047088 | ||
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