In the title coordination polymer, {[Eu(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Eu(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl-ate (hpc) trianion, two monodentate hpc anions and three water mol-ecules, forming a distorted bicapped trigonal-prismatic coordination geometry. The hpc ligands bridge adjacent Eu(III) ions, forming infinite double chains. Adjacent chains are further connected by hpc ligands into sheets. O-Hâ¯O hydrogen bonds then generate a three-dimensional supra-molecular framework.
Poly[[triaqua-(μ(3)-4-oxidopyridine-2,6-dicarboxyl-ato)europium(III)] monohydrate].
聚[[三水合-(α(3)-4-氧化吡啶-2,6-二羧酸根)铕(III)]一水合物]
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作者:Lv Dong-Yu, Gao Zhu-Qing, Gu Jin-Zhong
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Nov 30; 66(Pt 12):m1694-5 |
| doi: | 10.1107/S1600536810048518 | ||
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