In the title compound, [U(C(18)H(15)N(3)O(3)S)O(2)(C(2)H(5)OH)]·C(2)H(5)OH, the U(VI) ion is in a distorted penta-gonal-bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetra-dentate ligand and an O atom of an ethanol ligand form the equatorial plane. The dihedral angle between the mean planes of the two benzene rings is 34.8â (3)°. In the crystal, relatively strong O-Hâ¯O hydrogen bonds connect the complex and ethanol solvent mol-ecules into alternating centrosymmetric R(2) (2)(8) and R(4) (4)(16) ring motifs, forming chains along [100]. Weak inter-molecular C-Hâ¯O hydrogen bonds are also present.
[S-Allyl-4-(4-hy-droxy-2-oxidobenzyl-idene-κO)-1-(2-oxidobenzyl-idene-κO)isothio-semicarbazidato-κN,N](ethanol-κO)dioxido-uranium(VI) ethanol monosolvate.
[S-烯丙基-4-(4-羟基-2-氧化苄基-γO)-1-(2-氧化苄基-γO)异硫代氨基脲-γN,N](乙醇-γO)二氧化铀(VI)乙醇单溶剂合物
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作者:Takjoo Reza, Dutkiewicz Grzegorz, Kubicki Maciej
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):m1824-5 |
| doi: | 10.1107/S1600536811049579 | ||
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