In the title mol-ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe-C bond lengths compared with the unsubstituted ring. In the bromo-acetyl residue, the Br and O atoms are co-planar [the O-C-C-Br torsion angle is 5.7â (4)°] and are syn to each other. Helical supra-molecular chains along the b axis are formed in the crystal structure mediated by C-Hâ¯O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C-Hâ¯Ï(unsubstituted ring) inter-actions that stack along the a-axis direction.
(2-Bromo-acet-yl)ferrocene.
(2-溴乙酰基)二茂铁
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作者:Wu Xiang-Xiang, Zhu Xin, Ma Qiu-Juan, Ng Seik Weng, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):m1875 |
| doi: | 10.1107/S1600536811050434 | ||
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