The asymmetric unit of the title complex, [Ni(pht)(2)(pn)(2)] (pht is 5,5-diphenyl-hydantoinate and pn is propane-1,2-diamine) or [Ni(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], contains one-half [Ni(pht)(2)(pn)(2)] mol-ecule. The Ni(II) atom is situated on a crystallographic center of inversion and shows a distorted octa-hedral coordination geometry. A three-dimensional network structure is assembled by inter- and intra-molecular N-Hâ¯O=C inter-actions.
trans-Bis(5,5-diphenyl-hydantoinato-κN)bis-(propane-1,2-diamine-κN,N')nickel(II).
反式双(5,5-二苯基-乙内酰脲-γN)双-(丙烷-1,2-二胺-γN,N')镍(II)
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作者:Hu Xilan, Xu Xingyou, Wang Daqi, Li Xiaojiao
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Nov 29; 64(Pt 12):m1636 |
| doi: | 10.1107/S1600536808038749 | ||
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