In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl-amino)-benzoate anions, two nicotinamide ligands and two water mol-ecules in a slightly distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 3.09â (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10â (4)°. The uncoordinated water mol-ecule is linked to nicotinamide ligands by O-Hâ¯O hydrogen bonds. In the crystal, inter-molecular N-Hâ¯O, O-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. A weak N-Hâ¯Ï inter-action also occurs.
Diaqua-bis-[4-(dimethyl-amino)-benzoato-κO]bis-(nicotinamide-κN)zinc(II) dihydrate.
Diaqua-双-[4-(二甲基氨基)-苯甲酰-γO]双-(烟酰胺-γN)锌(II)二水合物
阅读:5
作者:Hökelek Tuncer, SaÄlam ErtuÄrul Gazi, Tercan BarıÅ, Aybirdi Ozgür, NecefoÄlu Hacali
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Nov 24; 66(Pt 12):m1636-7 |
| doi: | 10.1107/S1600536810046854 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
