The title Schiff base, C14H11NO3, crystallizes as a zwitterion (i.e. proton transfer from the carb-oxy-lic acid group to the imine N atom). The dihedral angle between the aromatic rings is 19.59â (6)° and an intra-molecular N-Hâ¯O hydrogen bond closes an S(6) ring. In the crystal, inversion dimers linked by pairs of O-Hâ¯O hydrogen bonds generate R 2 (4)(24) loops. The dimers are linked by C-Hâ¯O inter-actions, generating (211) sheets.
Crystal structure of (E)-2-[(4-hy-droxy-benzyl-idene)aza-nium-yl]benzoate.
(E)-2-[(4-羟基苄基亚甲基)氮杂鎓基]苯甲酸盐的晶体结构
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作者:Tahir M Nawaz, Khan Abdul Haleem, Shad Hazoor Ahmad
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Aug 16; 70(Pt 9):o1008 |
| doi: | 10.1107/S1600536814018273 | ||
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