The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxy-benzyl-idene)-5-(4-nitro-phen-yl)-1,3,4-thia-diazol-2-amine and diethyl phosphite. The thia-diazole and nitro-substituted phenyl rings in the mol-ecule are approximately coplanar, the dihedral angle being 5.3â (2)°. The dihedral angle formed by the mean plane through all non-H atoms of both the thia-diazole and the nitro-substituted phenyl ring with the plane of the meth-oxy-substituted phenyl ring is 48.9â (2)°. In the crystal structure, mol-ecules form centrosymmetric dimers as a result of N-Hâ¯O bonds involving amine H and phosphine oxide O atoms.
Diethyl {(4-methoxy-phen-yl)[5-(4-nitro-phen-yl)-1,3,4-thia-diazol-2-ylamino]meth-yl}phospho-nate.
二乙基{(4-甲氧基苯基)[5-(4-硝基苯基)-1,3,4-噻二唑-2-基氨基]甲基}膦酸酯
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作者:Yin Li-He, Wan Rong, Han Feng, Wang Bin, Wang Jin-Tang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Jul 5; 64(Pt 8):o1376 |
| doi: | 10.1107/S1600536808017364 | ||
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