In the title compound, C(24)H(29)BrO(6), the dihedral angle between the cyclo-hexenone mean planes is 57.63â (2)° while the dihedral angles between the benzene ring and the cyclo-hexenone mean planes are 58.42â (2) and 69.08â (3)°. The two cyclo-hexenone rings both show an envelope conformation, with the C atom bearing two methyl groups as the flap atom in each ring. Two intra-molecular O-Hâ¯O hydrogen bonds occur. In the crystal, molecules are linked via pairs of O-Hâ¯O hydrogen bonds, forming inversion dimers.
2,2'-[(3-Bromo-4-hy-droxy-5-meth-oxy-phen-yl)methyl-idene]bis-(3-hy-droxy-5,5-dimethyl-cyclo-hex-2-en-1-one).
2,2'-[(3-溴-4-羟基-5-甲氧基-苯基)甲基-亚甲基]双-(3-羟基-5,5-二甲基-环己-2-烯-1-酮)
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作者:Sughanya V, Sureshbabu N
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):o2875-6 |
| doi: | 10.1107/S1600536812037853 | ||
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