(S)-N-[1-(5-Benzyl-sulfan-yl-1,3,4-oxa-diazol-2-yl)-2-phenyl-eth-yl]-4-methyl-benzene-sulfonamide.

(S)-N-[1-(5-苄基硫基-1,3,4-噁二唑-2-基)-2-苯基乙基]-4-甲基苯磺酰胺

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作者:Syed Tayyaba, Hameed Shahid, Jones Peter G
The title compound, C(24)H(23)N(3)O(3)S(2), crystallizes with two independent mol-ecules in the asymmetric unit. They differ essentially in the orientation of the tolyl rings, between which there is π-π stacking (centroid-centroid distance = 3.01†à ). The absolute configuration was confirmed by the determination of the Flack parameter [x = 0.008†(9)]. In the crystal, mol-ecules are connected by two classical N-H⋯N hydrogen bonds and two weak but very short C-H⋯O(sulfon-yl) inter-actions, forming layers lying parallel to the bc plane.

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