The title compound, C(24)H(30)O(6), does not exhibit Ï-Ï inter-actions due to the steric effect of the bulky tert-butyl groups present in the mol-ecule. The presence of these groups at the 2 and 2' positions hinders the free motion of the benzene rings relative to each other, causing them to adopt an anti-periplanar arrangement. The benzene rings are twisted by just under 50.96â (17)° with respect to each other. The carbonyl groups within the mol-ecule are directed in different directions, one towards the biphenyl group and the other away from it. The mol-ecules are linked together by C=Oâ¯H-C hydrogen bonds.
Di-tert-butyl 2,2'-(biphenyl-2,2'-diyl-dioxy)diacetate.
二叔丁基 2,2'-(联苯-2,2'-二基-二氧基)二乙酸酯
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作者:Ali Qamar, Ibad Farooq, Shah Muhammad Raza, Vanderveer Donald
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Jul 5; 64(Pt 8):o1408 |
| doi: | 10.1107/S1600536808019764 | ||
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