In the title mol-ecule, C(20)H(18)ClN(3)O(2), the 2-chloro-phenyl group is disordered to a small extent [occupancies 0.875â (2)/0.125â (2)]. The phenyl-acetamide moiety is nearly planar due to a weak, intra-molecular C-Hâ¯O hydrogen bond. In the crystal, N-Hâ¯O hydrogen bonds and Ï-stacking inter-actions between pyridazine and phenyl rings form helical chains of mol-ecules in the b-axis direction, which are linked by C-Hâ¯O hydrogen bonds and C-Hâ¯Ï(ring) inter-actions. A Hirshfeld surface analysis was performed, which showed that Hâ¯H, Câ¯H/Hâ¯C and Oâ¯H/Hâ¯O inter-actions to dominate the inter-molecular contacts in the crystal.
Synthesis, crystal structure and Hirshfeld surface analysis of 2-{4-[(2-chloro-phen-yl)meth-yl]-3-methyl-6-oxopyridazin-1-yl}-N-phenyl-acetamide.
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作者:Assila Hamza, Zaoui Younes, Kalonji Mubengayi Camille, Guerrab Walid, Alsubari Abdulsalam, Mague Joel T, Ramli Youssef, Ansar Mhammed
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2024 | 起止号: | 2024 Oct 31; 80(Pt 11):1221-1225 |
| doi: | 10.1107/S2056989024010296 | ||
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