Synthesis, Spectroscopic, Thermal and Catalytic Properties of Four New Metal (II) Complexes with Selected N- and O-Donor Ligands

四种新型金属(II)配合物与选定的N-和O-供体配体的合成、光谱、热学和催化性质

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作者:Agnieszka Czylkowska, Bartłomiej Rogalewicz, Anita Raducka, Natalia Błaszczyk, Tomasz Maniecki, Kinga Wieczorek, Paweł Mierczyński

Abstract

Four solid compounds with formulae: Co(OAc)2(Im)·H2O (I), Ni(OAc)2(Im)1.5·2H2O (II), Cu2(OAc)4(Im) (III) and Zn(OAc)2(Im)·H2O (IV) (where: Im = 1H-Imidazole) were prepared and characterized by chemical and elemental analysis, powder X-ray diffraction patterns and FTIR spectroscopy. Catalytic properties of each complex for styrene oxidation reaction were investigated. Furthermore, thermal properties of compounds were studied using the TG-DTG and DSC techniques under dry air atmosphere. Additionally, volatile thermal decomposition and fragmentation products were also investigated using the TG-FTIR spectra in air.

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