Abstract
In nature, the interplay between individual organisms often leads to the emergence of complex belabours, of which sophistication has been refined through millions of years of evolution. Synthetic materials research has focused on mimicking the natural complexity, e.g., by harnessing non-equilibrium states to drive self-assembly processes. However, it is highly challenging to understand the interaction dynamics between non-equilibrium entities and to obtain collective behavior that can arise autonomously through interaction. In this study, thermally fueled, twisted rings exhibiting self-sustained movements are used as fundamental units and their interactive behaviors and emergent functions are investigated. The rings are fabricated from connected thermoresponsive liquid crystal elastomers (LCEs) strips that undergo zero-elastic-energy-mode, autonomous motions upon a heat gradient. Single-ring structures with various twisting numbers and nontrivial links, and connected knots where several LCE rings (N = 2,3,4,5) are studied and linked. The observations uncover that controlled locomotion of the structures can emerge when N ≥ 3. The locomotion can be programmed by controlling the handedness at the connection points between the individual rings. These findings illustrate how group activity emerges from individual responsive material components through mechanical coupling, offering a model for programming autonomous locomotion in soft matter constructs.