Abstract
We developed free-standing nitrogen-doped carbon nanofiber (CNF) electrodes incorporating Co/CoOx nanoparticles (NPs) as a new cathode material for removing Acid Orange 7 (AO7; a dye for wool) from wastewater by the heterogeneous electro-Fenton reaction. We produced the free-standing N-doped CNF electrodes by electrospinning a polyacrylonitrile (PAN) and cobalt acetate solution followed by thermal carbonation of the cobalt acetate/PAN nanofibers under a nitrogen atmosphere. We then investigated electro-Fenton-based removal of AO7 from wastewater with the free-standing N-doped-CNFs-Co/CoOx electrodes, in the presence or not of Fe2+ ions as a co-catalyst. The electrochemical analysis showed the high stability of the prepared N-doped-CNF-Co/CoOx electrodes in electrochemical oxidation experiments with excellent degradation of AO7 (20 mM) at acidic to near neutral pH values (3 and 6). Electro-Fenton oxidation at 10 mA/cm2 direct current for 40 min using the N-doped-CNF-Co/CoOx electrodes loaded with 25 wt% of Co/CoOx NPs led to complete AO7 solution decolorization with total organic carbon (TOC) removal values of 92.4% at pH 3 and 93.3% at pH 6. The newly developed N-doped-CNF-Co/CoOx electrodes are an effective alternative technique for wastewater pre-treatment before the biological treatment.