Synthesis and application of g-C(3)N(4)/Fe(3)O(4)/Ag nanocomposite for the efficient photocatalytic inactivation of Escherichia coli and Bacillus subtilis bacteria in aqueous solutions

合成gC(3)N(4)/Fe(3)O(4)/Ag纳米复合材料及其在水溶液中高效光催化灭活大肠杆菌和枯草芽孢杆菌的应用

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Abstract

Contamination of water with bacteria is one of the main causes of waterborne diseases. The photocatalytic method on the basis of bacterial inactivation seems to be a suitable disinfectant due to the lack of by-products formation. Herein, g-C(3)N(4)/Fe(3)O(4)/Ag nanocomposite combined with UV-light irradiation was applied for the inactivation two well-known bacteria namely, E. coli and B. subtilis. The nanocomposite was prepared by a hydrothermal method, and subsequently it was characterized by XRD, FT-IR, SEM, EDX and PL analyses. The optimum conditions established for the inactivation of both bacteria were as follows: nanocomposite dosage 3 g/L and bacterial density of 10(3) CFU/mL. In the meantime, the efficient inactivation of E. coli and B. subtilis took 30 and 150 min, respectively. The results also revealed that inactivation rate dropped with an increase in the bacterial density. It is also pointed out that OH˚ was found out to be the main radical species involved in the inactivation process. Finally, the kinetic results indicated that the inactivation of E. coli and B. subtilis followed the Weibull model. It is concluded that C(3)N(4)/Fe(3)O(4)/Ag nanocomposite along with UV-light irradiation is highly effective in inactivating E. coli and B. subtilis bacteria in the aqueous solutions.

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