Enhanced Electricity Generation and H(2)O(2) Production in a Photocatalytic Fuel Cell and Fenton Hybrid System Assisted with Reverse Electrodialysis

反向电渗析辅助的光催化燃料电池和芬顿混合系统中增强发电和H₂O₂生成

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Abstract

A novel integrating system coupled with photocatalytic fuel cell and Fenton system assisted by reverse electrodialysis (PREC) is proposed. The results demonstrate that H(2)O(2) concentration increased continuously in the reaction process to finally reach 960 mg/L and the current became stable at around 5.2 mA. The salinity-driven potential derived from the high concentration and low concentration cells in the hybrid system was 0.72 and 0.90 V respectively, at the salinity ratio of 50 and 100. The hybrid system has an energy recovery of 16%, a cathodic efficiency of 51%, and the maximum power of 76 W/m(2) at a salinity ratio of 50, with a 100 Ω external resistance. It is proved that PREC-Fenton possessed great potential in industrial wastewater treatment.

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